PETROLEUM EXPLORATION

New indexes and charts for genesis identification of multiple natural gases

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  • 1. Gas Geology Research Center of PetroChina Research Institute of Petroleum Exploration & Development, Langfang 065007, China;
    2. Key Laboratory of Gas Reservoir Formation and Development, CNPC, Langfang 065007, China;
    3. Information Center of PetroChina Research Institute of Petroleum Exploration & Development, Beijing 100083, China

Revised date: 2016-07-08

  Online published: 2017-07-27

Supported by

国家科技重大专项(2016ZX05007-003, 2011ZX05007-002); 中国石油天然气股份有限公司重大专项(2016B-0601, 2014B-0608)

Abstract

Identification of natural gas genesis and source for high-matured multiple natural gases is a great challenge in the exploration of deep-ultra deep and unconventional natural gases. In this paper, the genesis identification method system of multiple natural gases is enriched through new experimental techniques and comprehensive analysis of geological data. New indexes and charts of genesis identification for multiple natural gases were determined to distinguish the sapropelic kerogen degraded gas and crude oil cracking gas, accumulated and scattered liquid hydrocarbon cracking gas in different evolution stages, nitrogen, carbon dioxide of organic and inorganic origins, inert gases of crustal and mantled origins, coal-formed gas and oil-type gas by helium, nitrogen, carbon dioxide and mercury content in natural gas. These indexes and charts have been successfully applied in the Sichuan, Tarim and Songliao basins to identify the natural gas genesis and source for complicated gas reservoirs. The research results have provided effective support for the natural gas exploration in the Sinian-Cambrian ancient carbonate formations in the Sichuan Basin, deep formations in the Kuqa depression of the Tarim Basin, and deep volcanic formations in the Songliao Basin.

Cite this article

LI Jian1, 2, LI Zhisheng1, 2, WANG Xiaobo1, 2, WANG Dongliang3, XIE Zengye1, 2, LI Jin1, 2, WANG Yifeng1, 2, HAN Zhongxi1, 2, MA Chenghua1, 2, WANG Zhihong1, 2, CUI Huiying1, 2, WANG Rong1, 2, HAO Aisheng1, 2 . New indexes and charts for genesis identification of multiple natural gases[J]. Petroleum Exploration and Development, 2017 , 44(4) : 503 -512 . DOI: 10.11698/PED.2017.04.03

References

[1] GALIMOV E M. Izotopy Ugleroda v Neftegazovoy Geologii (Carbon isotopes in petroleum geology)[M]. Moscow: Mineral Press, 1973: 384.
[2] STAHL W J. Carbon and nitrogen isotopes in hydrocarbon research and exploration[J]. Chemical Geology, 1977, 20(77): 121-149.
[3] WELHAN J A, CRAIG H. Methane, hydrogen and helium in hydrothermal fluids at 21°N on the East Pacific Rise[M]// RONA P A, BOSTROM K, LAUBIER L. Hydrothermal processes at seafloor spreading centers. New York: Plenum Press, 1983: 391-410.
[4] 戴金星. 各类烷烃气的鉴别[J]. 中国科学: 化学, 1992, 22(2): 185-193.
DAI Jinxing. Identification of different alkane gas[J]. SCIENCE CHINA Chemistry, 1992, 35(10): 1246-1257.
[5] 徐永昌, 沈平, 刘文汇, 等. 天然气中稀有气体地球化学研究[M]. 北京: 科学出版社, 1998.
XU Yongchang, SHEN Ping, LIU Wenhui, et al. Noble gas geochemistry in natural gases[M]. Beijing: Science Press, 1998.
[6] 刘文汇, 徐永昌. 天然气成因类型及判别标志[J]. 沉积学报, 1996, 14(1): 110-116.
LIU Wenhui, XU Yongchang. Genetic indicators for natural gases[J]. Acta Sedimentologica Sinica, 1996, 14(1): 110-116.
[7] DAI Jinxing, YANG Shunfeng, CHEN Hanlin, et al. Geochemistry and occurrence of inorganic gas accumulations in Chinese sedimentary basins[J]. Organic Geochemistry, 2005, 36(12): 1664-1688.
[8] 戴金星, 邹才能, 张水昌, 等. 无机成因和有机成因烷烃气的鉴别[J]. 中国科学: 地球科学, 2008, 38(11): 1329-1341.
DAI Jinxing, ZOU Caineng, ZHANG Shuichang, et al. Discrimination of abiogenic and biogenic alkane gases[J]. SCIENCE CHINA Earth Sciences, 2008, 51(12): 1737-1749.
[9] 戴金星. 中国煤成大气田及气源[M]. 北京: 科学出版社, 2014.
DAI Jinxing. Gaint coal-derived gas fields and their gas sources in China [M]. Beijing:Science Press, 2014.
[10] 李剑, 罗霞, 李志生, 等. 对甲苯碳同位素值作为气源对比指标的新认识[J]. 天然气地球科学, 2003,14(3): 177-180.
LI Jian, LUO Xia, LI Zhisheng, et al. New issue of carbon isotope composition of toluene to be as index of gas-rock correlation[J]. Natural Gas Geoscience, 2003, 14(3): 177-180.
[11] 胡国艺, 李剑, 李谨, 等. 判识天然气成因的轻烃指标探讨[J]. 中国科学: 地球科学, 2007, 37(S2): 111-117.
HU Guoyi, LI Jian, LI Jin, et al. Preliminary study on the origin identification of natural gas by the parameters of light hydrocarbon [J]. SCIENCE CHINA Earth Sciences, 2008, 51(1): 131-139.
[12] PRINZHOFER A A, HUC A Y. Genetic and post-genetic molecular and isotopic fractionations in natural gases[J]. Chemical Geology, 1995, 126(3): 281-290.
[13] BEHAR F, UNGERER P, KRESSMANN S, et al. Thermal evolution of crude oils in sedimentary basins: Experimental simulation in a confined system and kinetic modeling[J]. Revue De L' Institut Francais Du Petrole, 1991, 46(2): 151-181.
[14] 杜金虎, 邹才能, 徐春春, 等. 川中古隆起龙王庙组特大型气田战略发现与理论技术创新[J]. 石油勘探与开发, 2014, 41(3): 268-277.
DU Jinhu, ZOU Caineng, XU Chunchun, et al. Theoretical and technical innovations in strategic discovery of huge gas fields in Longwangmiao Formation of central Sichuan paleo-uplift, Sichuan Basin[J]. Petroleum Exploration and Development, 2014, 41(3): 268-277.
[15] 邹才能, 杜金虎, 徐春春, 等. 四川盆地震旦系—寒武系特大型气田形成分布、资源潜力及勘探发现[J]. 石油勘探与开发, 2014, 41(3): 278-293.
ZOU Caineng, DU Jinhu, XU Chunchun, et al. Formation, distribution, resource potential and discovery of the Sinian-Cambrian giant gas field, Sichuan Basin, SW China[J]. Petroleum Exploration and Development, 2014, 41(3): 278-293.
[16] 魏国齐, 谢增业, 宋家荣, 等. 四川盆地川中古隆起震旦系—寒武系天然气特征及成因[J]. 石油勘探与开发, 2015, 42(6): 702-711.
WEI Guoqi, XIE Zengye, SONG Jiarong, et al. Features and origin of natural gas in the Sinian-Cambrian of central Sichuan paleo-uplift, Sichuan Basin, SW China[J]. Petroleum Exploration and Development, 2015, 42(6): 702-711.
[17] 赵文智, 王兆云, 王东良, 等. 分散液态烃的成藏地位与意义[J]. 石油勘探与开发, 2015, 42(4): 401-413.
ZHAO Wenzhi, WANG Zhaoyun, WANG Dongliang, et al. Contribution and significane of dispersed liquid hydrocarbons to reservoir formation[J]. Petroleum Exploration and Development, 2015, 42(4): 401-413.
[18] 李贤庆, 仰云峰, 冯松宝, 等. 塔里木盆地原油裂解生烃特征与生气过程研究[J]. 中国矿业大学学报, 2012, 41(3): 397-405.
LI Xianqing, YANG Yunfeng, FENG Songbao, et al. Characteristics of hydrocarbon and gas generation process from pyrolyzed crude oils in Tarim basin[J]. Journal of China University of Mining & Technology, 2012, 41(3): 397-405.
[19] 胡国艺, 李志生, 罗霞, 等. 两种热模拟体系下有机质生气特征对比[J]. 沉积学报, 2004, 22(4): 718-723.
HU Guoyi, LI Zhisheng, LUO Xia, et al. The comparision of gas generation potential and model between two different thermal simulation systems[J]. Acta Sedimentologica Sinica, 2004, 22(4): 718-723.
[20] PAN Changchun, JIANG Lanlan, LIU Jinzhong, et al. The effect of calcite and montmorillonite on oil cracking in confined pyrolysis experiments[J]. Organic Geochemistry, 2010, 41(7): 611-626.
[21] 谢增业, 李志生, 国建英, 等. 烃源岩和储层中沥青形成演化实验模拟及其意义[J]. 天然气地球科学, 2016, 27(8): 1489-1499.
XIE Zengye, LI Zhisheng, GUO Jianying, et al. Experimental simulation and significane on bitumen formation in source rock and reservoir[J]. Natural gas Geosicence, 2016, 27(8): 1489-1499.
[22] 张子枢. 气藏中氮的地质地球化学[J]. 地质地球化学, 1988, 16(2): 51-56.
ZHANG Zishu. Geological geochemistry of nitrogen in gas reservoir [J]. Geology Geochemistry, 1988, 16(2): 51-56.
[23] 杜建国, 刘文汇, 邵波. 天然气中氮的地球化学特征[J]. 沉积学报, 1996, 14(1): 143-147.
DU Jianguo, LIU Wenhui, SHAO Bo. Geochmical charateristics of nitrogen in natural gases[J]. Acta Sedimentologica Sinica, 1996, 14(1): 143-147.
[24] 朱岳年. 天然气中分子氮成因及判识[J]. 中国石油大学学报(自然科学版), 1999, 23(2): 23-26.
ZHU Yuenian. Genesis and identification of molecular nitrogen in natural gases[J]. Journal of China University of Petroleum (Edition of Natural Science), 1999, 23(2): 23-26.
[25] 何家雄, 陈伟煌, 李明兴. 莺—琼盆地天然气成因类型及气源剖析[J]. 中国海上油气(地质), 2000, 14(6): 398-405.
HE Jiaxiong, CHEN Weihuang, LI Mingxing. Genesis and their gas source analysis of natural gases in Ying-Qiong Basin[J]. China Offshore Oil and Gas (Geology), 2000, 14(6): 398-405.
[26] 李谨, 李志生, 王东良, 等. 塔里木盆地含氮天然气地球化学特征及氮气来源[J]. 石油学报, 2013, 34(S1): 102-111.
LI Jin, LI Zhisheng, WANG Dongliang, et al. Geochemical charateristics and N 2 source of nitrogen riched natural gas in Tarim Basin[J]. Acta Perolei Sinica, 2013, 34(S1): 102-111.
[27] JENDEN P D, KAPLAN I R, POREDA R J, et al. Origin of nitrogen-rich natural gases in the California Great Valley: Evidence from helium, carbon and nitrogen isotope ratios[J]. Geochimica et Cosmochimica Acta, 1988, 52(4): 851-861.
[28] 戴金星. 云南腾冲县硫磺塘天然气碳同位素组成特征和成因[J]. 科学通报, 1988, 33(15): 1168-1170.
DAI Jinxing. Composition characteristics and origin of carbon isotope of Liuhuangtang natural gas in Tengchong County, Yunnan Province[J]. Chinese Science Bulletin, 1989, 34(12): 1027-1030.
[29] CRAIG H. Isotopic variations in meteoric waters[J]. Science, 1961, 133(3465): 1702-1703.
[30] BOTTINGA Y, JAVOY M. Oxygen isotope partitioning among the minerals in igneous and metamorphic rocks[J]. Reviews of Geophysics and Space Physics, 1975, 13(13): 401-418.
[31] TAYLOR H P. The oxygen isotope geochemistry of igneous rocks [J]. Contributions to Mineralogy and Petrology, 1968, 19(1): 1-71.
[32] HOEFS J. Stable isotope geochemistry[M]. 5th ed. Berlin: Springer, 2004.
[33] 郑永飞, 陈江峰. 稳定同位素地球化学[M]. 北京: 科学出版社, 2000.
ZHENG Yongfei, CHEN Jiangfeng. Stable isotope geochemistry[M]. Beijing: Science Press, 2000.
[34] 李谨, 李志生, 王东良, 等. 天然气中CO 2 氧同位素在线检测技术与应用[J]. 石油学报, 2014, 35(1): 68-75.
LI Jin, LI Zhisheng, WANG Dongliang, et al. On-line detection of oxygen isotope of CO 2 in natural gases and its application[J]. Acta Perolei Sinica, 2014, 35(1): 68-75.
[35] MAMYRIN B A, ANUFRRIEV G S, KAMENSKII I L, et al. Determination of the isotopic composition of atmospheric helium [J]. Geochemistry International, 1970, 7(4): 465-473.
[36] CLARKE W B, JENKINS W J, TOP Z. Determination of tritium by mass spectrometric measurement of 3 He[J]. The International Journal of Applied Radiation and Isotopes, 1976, 27(9): 515-522.
[37] 徐永昌, 王先彬, 吴仁铭, 等. 天然气中稀有气体同位素[J]. 地球化学, 1979, 8(4): 271-282.
XU Yongchang, WANG Xianbin, WU Renming, et al. Rare gas isotopic composition of natural gases[J]. Geochemica, 1979, 8(4): 271-282.
[38] OZIMA M, PODESEK F A. Noble gas geochemistry[M]. London: Cambridge University Press, 1983.
[39] KENNEDY B M, HIYAGON H, REYNOLDS J H. Crustal neon: A striking uniformity[J]. Earth and Planetary Science Letters, 1990, 98(3): 277-286.
[40] 徐胜, 徐永昌, 沈平, 等.中国东部盆地天然气中氖同位素组成及其地质意义[J]. 科学通报, 1996, 41(21) : 1970-1972.
XU Sheng, XU Yongchang, SHEN Ping, et al. Neon isotopes and its geological significane in natural gases in eastern China[J]. Chinese Science Bulletin, 1996, 41(21): 1970-1972.
[41] 王晓波, 李志生, 李剑, 等. 稀有气体全组分含量及同位素分析技术[J]. 石油学报, 2013, 34(S1): 70-77.
WANG Xiaobo, LI Zhisheng, LI Jian, et al. Techniques for total composition and isotope analyses of noble gases[J]. Acta Perolei Sinica, 2013, 34(S1): 70-77.
[42] 魏国齐, 王东良, 王晓波,等. 四川盆地高石梯—磨溪大气田稀有气体特征[J]. 石油勘探与开发, 2014, 41(5): 533-538.
WEI Guoqi, WANG Dongliang, WANG Xiaobo, et al. Characteristics of noble gases in the large Gaoshiti-Moxigas field in Sichuan Basin, SW China[J]. Petroleum Exploration and Development, 2014, 41(5): 533-538.
[43] WANG Xiaobo, CHEN Jianfa, LI Zhisheng, et al. Rare gases geochemical characteristics and gas source correlation for Dabei gas field in Kuche depression, Tarim Basin[J]. Energy Exploration & Exploitation, 2016, 34(1): 113-128.
[44] 陈践发, 徐学敏, 师生宝. 不同沉积环境下原油氮同位素的地球化学特征[J]. 中国石油大学学报(自然科学版), 2015, 39(5): 1-6.
CHEN Jianfa, XU Xuemin, SHI Shengbao. Geochemical characteristics of nitrogen isotope of crude oils in different depositional environments[J]. Journal of China University of Petroleum (Edition of Natural Science), 2015, 39(5): 1-6.
[45] 李剑, 韩中喜, 严启团, 等. 中国气田天然气中汞的成因模式[J]. 天然气地球科学, 2012, 23(3): 413-419.
LI Jian, HAN Zhongxi, YAN Qituan, et al. Genesis of mercury in natural gas of Chinese gas fields[J]. Natrual Gas Geoscience, 2012, 23(3): 413-419.
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