COMPREHENSIVE RESEARCH

Quantitative characterization of micro forces in shale hydration and field applications

  • KANG Yili ,
  • YANG Bin ,
  • LI Xiangchen ,
  • YANG Jian ,
  • YOU Lijun ,
  • CHEN Qiang
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  • 1. State Key Laboratory of Oil & Gas Reservoir Geology and Exploitation in Southwest Petroleum University, Chengdu 610500, China;
    2. Engineering Technology Research Institute of CNPC Southwest Oil & Gas Field Company, Guanghan 618300, China

Received date: 2016-08-25

  Revised date: 2017-01-10

  Online published: 2017-05-22

Abstract

Shales (illite was the dominant clay mineral) of Silurian Longmaxi Formation in Sichuan Basin and Triassic Yanchang Formation in Ordos Basin were taken as subjects to examine the mechanisms of shale-water interaction, quantitative characterization of hydration force and potential field applications based on micro forces analyses. Mica sheet with composition and property very similar to illite was tested for micro forces between the crystal layers. In electrolyte solution, micro forces between mica-solution-mica system include DLVO (Derjaguin-Landau-Verwey-Overbeek) force and hydration force; when the electrolyte concentration was low, the tested curve agreed with the theoretical DLVO curve; when the electrolyte concentration was higher than the critical value and the distance between mica sheets was less than 5 nm, the tested curve deviated from the DLVO curve completely, and the hydration force became dominant. Quantitative analysis indicated that the hydration force decayed in a rapid double-exponential type with the growth of distance. Field applications indicate that strict control of water invasion and reducing the strength of hydration force are the keys in designing collapse-preventing drilling fluids; meanwhile, during the shut-in period of shale gas wells, shale-water interaction can induce and extend micro-cracks, further improving the stimulation effect of shale reservoirs.

Cite this article

KANG Yili , YANG Bin , LI Xiangchen , YANG Jian , YOU Lijun , CHEN Qiang . Quantitative characterization of micro forces in shale hydration and field applications[J]. Petroleum Exploration and Development, 2017 , 44(2) : 301 -308 . DOI: 10.11698/PED.2017.02.17

References

[1] CHENEVERT M E. Shale alteration by water adsorption[J]. Journal of Petroleum Technology, 1970, 22(1): 141-148.
[2] 孟英峰. 泥页岩水化反应的系统仿真技术及其在油气田开发领域中的应用[D]. 成都: 西南石油学院, 2002.
MENG Yingfeng. Simulation technology of shale-water interaction and its application in oilfield[D]. Chengdu: Southwest Petroleum University, 2002.
[3] ISRAELACHVILI J N. Intermolecular and surface forces[M]. Singapore: Elsevier (Singapore) Pte Ltd., 2012.
[4] ISRAELACHVILI J N, PASHLEY R M. Molecular layering of water at surfaces and origin of repulsive hydration forces[J]. Nature, 1983, 306(17): 249-250.
[5] 鄢捷年. 钻井液工艺学[M]. 东营: 石油大学出版社, 2001.
YAN Jienian. Drilling fluid technology[M]. Dongying: University of Petroleum Press, 2001.
[6] JELLANDER R, MARČELJA S, QUIRK J. Attractive double-layer interactions between calcium clay particles[J]. Journal of Colloid & Interface Science, 1988, 126(1): 194-211.
[7] DARLEY H. A laboratory investigation of borehole stability[J]. Journal of Petroleum Technology, 1969, 21(7): 883-892.
[8] PASHLEY R M. DLVO and hydration forces between mica surfaces in Li + , Na + , K + , and Cs + electrolyte solutions: A correlation of double-layer and hydration forces with surface cation exchange properties[J]. Journal of Colloid & Interface Science, 1981, 83(2): 531-546.
[9] LI Y, FU Y, TANG G, et al. Effect of weak bedding planes on wellbore stability for shale gas wells[R]. SPE 155666, 2012.
[10] 石秉忠, 夏柏如, 林永学, 等. 硬脆性泥页岩水化裂缝发展CT成像与机理[J]. 石油学报, 2012, 33(1): 137-142.
SHI Bingzhong, XIA Bairu, LIN Yongxue, et al. CT imaging and mechanism analysis of crack development by hydration in hard- brittle shale formations[J]. Acta Petrolei Sinica, 2012, 33(1): 137-142.
[11] KILPATRICK J I, LOH S H, JARVIS S P. Directly probing the effects of ions on hydration forces at interfaces[J]. Journal of the American Chemical Society, 2013, 135(7): 2628-2634.
[12] PASHLEY R, QUIRK J. The effect of cation valency on DLVO and hydration forces between macroscopic sheets of muscovite mica in relation to clay swelling[J]. Colloids and Surfaces, 1984, 9(1): 1-17.
[13] 王行信, 辛国强, 冯永才. 松辽盆地粘土矿物研究[M]. 哈尔滨: 黑龙江科学技术出版社, 1990.
WANG Xingxin, XIN Guoqiang, FENG Yongcai. Clay mineral investigation in Songliao Basin[M]. Harbin: Heilongjiang Science Press, 1990.
[14] ZOLFAGHARI A, DEHGHANPOUR H, NOEL M, et al. Laboratory and field analysis of flowback water from gas shales[J]. Journal of Unconventional Oil and Gas Resources, 2016, 14: 113-127.
[15] ZOLFAGHARI A, TANG Y, HOLYK J, et al. Advances in flowback chemical analysis of gas shales[R]. SPE 175154, 2015.
[16] DISHON M, ZOHAR O, SIVAN U. From repulsion to attraction and back to repulsion: The effect of NaCl, KCl, and CsCl on the force between silica surfaces in aqueous solution[J]. Langmuir, 2009, 25(5): 2831-2836.
[17] PASHLEY R M, ISRAELACHVILI J N. DLVO and hydration forces between mica surfaces in Mg 2+ , Ca 2+ , Sr 2+ , and Ba 2+ chloride solutions[J]. Journal of Colloid & Interface Science, 1984, 97(2): 446-455.
[18] KJELLANDER R, MARČELJA S, QUIRK J R. A theoretical and experimental study of forces between charged mica surfaces in aqueous CaCl 2 solutions[J]. The Journal of Chemical Physics, 1990, 92(7): 4399-4407.
[19] HORN R G. Surface forces and their action in ceramic materials[J]. Journal of the American Ceramic Society, 1990, 73(5): 1117-1135.
[20] VIANI B E, LOW P F, ROTH C B. Direct measurement of the relation between interlayer force and interlayer distance in the swelling of montmorillonite[J]. Journal of Colloid & Interface Science, 1983, 96(1): 229-244.
[21] YUAN Weina, LI Xiao, PAN Zhejun, et al. Experimental investigation of interactions between water and a lower Silurian Chinese shale[J]. Energy & Fuels, 2014, 28(8): 4925-4933.
[22] GHANBARI E, DEHGHANPOUR H. Impact of rock fabric on water imbibition and salt diffusion in gas shales[J]. International Journal of Coal Geology, 2015, 138: 55-67.
[23] 刘向君, 熊健, 梁利喜. 龙马溪组硬脆性页岩水化实验研究[J]. 西南石油大学学报(自然科学版), 2016, 38(3): 178-186.
LIU Xiangjun, XIONG Jian, LIANG Lixi. Hydration experiment of hard brittle shale of the Longmaxi Formation[J]. Journal of Southwest Petroleum University (Science & Technology Edition), 2016, 38(3): 178-186.
[24] 侯振坤, 杨春和, 郭印同, 等. 单轴压缩下龙马溪组页岩各向异性特征研究[J]. 岩土力学, 2015, 36(9): 2541-2550.
HOU Zhenkun, YANG Chunhe, GUO Yintong, et al. Experimental study on anisotropic properties of Longmaxi formation shale under uniaxial compression[J]. Rock and Soil Mechanics, 2015, 36(9): 2541-2550.
[25] 康毅力, 陈强, 游利军, 等. 钻井液作用下页岩破裂失稳行为试验[J]. 中国石油大学学报(自然科学版), 2016, 40(4): 45-53.
KANG Yili, CHEN Qiang, YOU Lijun, et al. Laboratory studies of shale fracturing behaviors with rock-drilling fluid interactions[J]. Journal of China University of Petroleum (Edition of Natural Sciences), 2016, 40(4): 45-53.
[26] 温航, 陈勉, 金衍, 等. 硬脆性泥页岩斜井段井壁稳定力化耦合研究[J]. 石油勘探与开发, 2014, 41(6): 748-754.
WEN Hang, CHEN Mian, JIN Yan, et al. A chemo-mechanical coupling model of deviated borehole stability in hard brittle shale[J]. Petroleum Exploration and Development, 2014, 41(6): 748-754.
[27] 史凯娇, 徐同台, 臧伟伟. 甲酸铯盐水与钻井液处理剂配伍性研究[J]. 天然气工业, 2010, 30(12): 72-76.
SHI Kaijiao, XU Tongtai, ZANG Weiwei. Compatibility studies of Cesium formate brine and drilling fluid treating agents[J]. Natural Gas Industry, 2010, 30(12): 72-76.
[28] 南小宁, 郑力会, 童庆恒. 硅酸盐钻井液技术发展机遇与挑战[J]. 钻采工艺, 2015, 38(6): 75-78.
NAN Xiaoning, ZHENG Lihui, TONG Qingheng. Development opportunity and challenges of silicate drilling fluid[J]. Drilling & Production Technology, 2015, 38(6): 75-78.
[29] 邹才能, 董大忠, 王玉满, 等. 中国页岩气特征、挑战及前景(二)[J]. 石油勘探与开发, 2016, 43(2): 166-178.
ZOU Caineng, DONG Dazhong, WANG Yuman, et al. Shale gas in China: Characteristics, challenges and prospects (Ⅱ)[J]. Petroleum Exploration and Development, 2016, 43(2): 166-178.
[30] CHENG Y. Impact of water dynamics in fractures on the performance of hydraulically fractured wells in gas-shale reservoirs[J]. Journal of Canadian Petroleum Technology, 2012, 51(2): 143-151.
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