Microscopic mechanisms of intra-source micro-migration and enrichment of lacustrine shale oil: A case study of Chang73 in the Ordos Basin, NW China

Expand
  • 1. Key Laboratory of Deep Petroleum Intelligent Exploration and Development, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China;
    2. College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China;
    3. PetroChina Changqing Oilfield Company, Xi'an 710018

Received date: 2024-05-06

  Revised date: 2025-07-18

  Online published: 2025-08-26

Abstract

Lacustrine shale oil in China exhibits a huge resource potential but a highly heterogeneous distribution. Deciphering its intra-source micro-migration and enrichment mechanisms is crucial for accurately predicting geological sweet spots. Taking the Chang73 submember of the Yanchang Formation in the Ordos Basin as an example, we integrated high-resolution scanning electron microscopy (SEM), optical microscopy, laser Raman spectroscopy, rock pyrolysis, and organic solvent extraction experiments to identify solid bitumen of varying origins, obtain direct evidence of intra-source micro-migration of shale oil, and establish the coupling between the shale nano/micro-fabric and the oil generation, micro-migration and accumulation. The results show that the Chang73 shale with rich alginite in laminae has the highest hydrocarbon generation potential but a low thermal transformation ratio. Frequent alternations of micron-scale argillaceous-felsic laminae enhance expulsion efficiency, yielding consistent aromaticity between in-situ and migrated solid bitumen. Argillaceous laminae rich in terrestrial organic matter (OM) and clay minerals exhibit lower hydrocarbon generation threshold but stronger hydrocarbon retention capacity, with a certain amount of light oil/bitumen preserved to differentiate the chemical structure of in-situ versus migrated bitumen. Tuffaceous and sandy laminae contain abundant felsic minerals and migrated solid bitumen. Tuffaceous laminae develop high-angle microfractures under shale overpressure, facilitating oil charging into rigid mineral intergranular pores of sandy laminae. Fractionation during micro-migration progressively decreases the aromaticity of solid bitumen from shale, through tuffaceous and argillaceous, to sandy laminae, while increasing light hydrocarbon components and enhancing OM-hosted pore development. The intra-source micro-migration and enrichment of the Chang73 shale oil result from synergistic organic-inorganic diagenesis, with compositional fractionation being a key mechanism for forming laminated sweet spots.

Cite this article

WANG Yingzhu, HOU Yuting, YANG Jijin . Microscopic mechanisms of intra-source micro-migration and enrichment of lacustrine shale oil: A case study of Chang73 in the Ordos Basin, NW China[J]. Petroleum Exploration and Development, 0 : 20251003 -20251003 . DOI: 10.11698/PED.20240297

References

[1] 胡素云, 赵文智, 侯连华, 等. 中国陆相页岩油发展潜力与技术对策[J]. 石油勘探与开发, 2020, 47(4): 819-828.
HU Suyun, ZHAO Wenzhi, HOU Lianhua, et al.Development potential and technical strategy of continental shale oil in China[J]. Petroleum Exploration and Development, 2020, 47(4): 819-828.
[2] 邹才能, 杨智, 董大忠, 等. 非常规源岩层系油气形成分布与前景展望[J]. 地球科学, 2022, 47(5): 1517-1533.
ZOU Caineng, YANG Zhi, DONG Dazhong, et al.Formation, distribution and prospect of unconventional hydrocarbons in source rock strata in China[J]. Earth Science, 2022, 47(5): 1517-1533.
[3] 潘松圻, 郭秋雷, 邹才能, 等. 页岩型与粉砂岩型 “页岩油系统” 甜点段判识: 以鄂尔多斯盆地长7段为例[J]. 中国科学: 地球科学, 2023, 53(7): 1663-1678.
PAN Songqi, GUO Qiulei, ZOU Caineng, et al.Identification of sweet spots in shale-type and siltstone-type “shale oil systems”: A case study of the Chang 7 member in Ordos Basin[J]. SCIENCE CHINA Earth Sciences, 2023, 66(7): 1647-1663.
[4] 金之钧, 王冠平, 刘光祥, 等. 中国陆相页岩油研究进展与关键科学问题[J]. 石油学报, 2021, 42(7): 821-835.
JIN Zhijun, WANG Guanping, LIU Guangxiang, et al.Research progress and key scientific issues of continental shale oil in China[J]. Acta Petrolei Sinica, 2021, 42(7): 821-835.
[5] 刘全有, 李鹏, 金之钧, 等. 湖相泥页岩层系富有机质形成与烃类富集: 以长7为例[J]. 中国科学: 地球科学, 2022, 52(2): 270-290.
LIU Quanyou, LI Peng, JIN Zhijun, et al.Organic-rich formation and hydrocarbon enrichment of lacustrine shale strata: A case study of Chang 7 member[J]. SCIENCE CHINA Earth Sciences, 2022, 65(1): 118-138.
[6] GUO Q L, YAO Y, HOU L H, et al.Oil migration, retention, and differential accumulation in “sandwiched” lacustrine shale oil systems from the Chang 7 member of the Upper Triassic Yanchang Formation, Ordos Basin, China[J]. International Journal of Coal Geology, 2022, 261: 104077.
[7] 郭旭升, 马晓潇, 黎茂稳, 等. 陆相页岩油富集机理探讨[J]. 石油与天然气地质, 2023, 44(6): 1333-1349.
GUO Xusheng, MA Xiaoxiao, LI Maowen, et al.Mechanisms for lacustrine shale oil enrichment in Chinese sedimentary basins[J]. Oil & Gas Geology, 2023, 44(6): 1333-1349.
[8] 葸克来, 李克, 操应长, 等. 鄂尔多斯盆地三叠系延长组长73亚段富有机质页岩纹层组合与页岩油富集模式[J]. 石油勘探与开发, 2020, 47(6): 1244-1255.
XI Kelai, LI Ke, CAO Yingchang, et al.Laminae combination and shale oil enrichment patterns of Chang 73 sub-member organic-rich shales in the Triassic Yanchang Formation, Ordos Basin, NW China[J]. Petroleum Exploration and Development, 2020, 47(6): 1244-1255.
[9] 李士祥, 郭芪恒, 潘松圻, 等. 烃类源内微运移对页理型页岩油差异富集的影响: 以鄂尔多斯盆地三叠系延长组长73亚段为例[J]. 中国石油勘探, 2023, 28(4): 46-54.
LI Shixiang, GUO Qiheng, PAN Songqi, et al.Influence of intrasource micro-migration of hydrocarbons on the differential enrichment of laminated type shale oil: A case study of the third sub-member of the seventh member of the Triassic Yanchang Formation in Ordos Basin[J]. China Petroleum Exploration, 2023, 28(4): 46-54.
[10] 胡涛, 姜福杰, 庞雄奇, 等. 页岩油微运移识别、评价及其石油地质意义[J]. 石油勘探与开发, 2024, 51(1): 114-126.
HU Tao, JIANG Fujie, PANG Xiongqi, et al.Identification and evaluation of shale oil micro-migration and its petroleum geological significance[J]. Petroleum Exploration and Development, 2024, 51(1): 114-126.
[11] JUBB A M, HACKLEY P C, HATCHERIAN J J, et al.Nanoscale molecular fractionation of organic matter within unconventional petroleum source beds[J]. Energy & Fuels, 2019, 33(10): 9759-9766.
[12] ZOU C N, PAN S Q, HORSFIELD B, et al.Oil retention and intrasource migration in the organic-rich lacustrine Chang 7 shale of the Upper Triassic Yanchang Formation, Ordos Basin, central China[J]. AAPG Bulletin, 2019, 103(11): 2627-2663.
[13] SANDVIK E I, YOUNG W A, CURRY D J.Expulsion from hydrocarbon sources: The role of organic absorption[J]. Organic Geochemistry, 1992, 19(1/3): 77-87.
[14] PEPPER A S, CORVI P J.Simple kinetic models of petroleum formation. Part III: Modelling an open system[J]. Marine and Petroleum Geology, 1995, 12(4): 417-452.
[15] PAN Y H, LI M W, SUN Y G, et al.Characterization of free and bound bitumen fractions in a thermal maturation shale sequence. Part 1: Acidic and neutral compounds by negative-ion ESI FT-ICR MS[J]. Organic Geochemistry, 2019, 134: 1-15.
[16] HU T, JING Z H, ZHANG Q, et al.Shale oil micro-migration characterization: Key methods and outlook[J]. Advances in Geo-Energy Research, 2025, 15(1): 5-12.
[17] HU S Z, LI S F, XIA L W, et al.On the internal oil migration in shale systems and implications for shale oil accumulation: A combined petrological and geochemical investigation in the Eocene Nanxiang Basin, China[J]. Journal of Petroleum Science and Engineering, 2020, 184: 106493.
[18] ZHANG T W, FU Q L, SUN X, et al.Meter-scale lithofacies cycle and controls on variations in oil saturation, Wolfcamp A, Delaware and Midland basins[J]. AAPG Bulletin, 2021, 105(9): 1821-1846.
[19] HACKLEY P C, VALENTINE B J, HATCHERIAN J J.On the petrographic distinction of bituminite from solid bitumen in immature to early mature source rocks[J]. International Journal of Coal Geology, 2018, 196: 232-245.
[20] 郭芪恒, 李士祥, 金振奎, 等. 鄂尔多斯盆地延长组长73亚段页岩油特征及勘探方向[J]. 石油勘探与开发, 2023, 50(4): 767-781.
GUO Qiheng, LI Shixiang, JIN Zhenkui, et al.Characteristics and exploration targets of Chang 7 shale oil in Triassic Yanchang Formation, Ordos Basin, NW China[J]. Petroleum Exploration and Development, 2023, 50(4): 767-781.
[21] STOKES M R, VALENTINE B J, HACKLEY P C, et al.Relating systematic compositional variability to the textural occurrence of solid bitumen in shales[J]. International Journal of Coal Geology, 2022, 261: 104068.
[22] SIMON R E, JOHNSON S C, KHATIB O, et al.Correlative nano-spectroscopic imaging of heterogeneity in migrated petroleum in unconventional reservoir pores[J]. Fuel, 2021, 300: 120836.
[23] KATZ B J, ARANGO I.Organic porosity: A geochemist’s view of the current state of understanding[J]. Organic Geochemistry, 2018, 123: 1-16.
[24] MASTALERZ M, DROBNIAK A, STANKIEWICZ A B.Origin, properties, and implications of solid bitumen in source-rock reservoirs: A review[J]. International Journal of Coal Geology, 2018, 195: 14-36.
[25] LIU B, MASTALERZ M, SCHIEBER J.SEM petrography of dispersed organic matter in black shales: A review[J]. Earth-Science Reviews, 2022, 224: 103874.
[26] WANG Y Z, YANG J I.Origin of organic matter pore heterogeneity in oil mature Triassic Chang-7 mudstones, Ordos Basin, China[J]. International Journal of Coal Geology, 2024, 283: 104458.
[27] 刘贝. 泥页岩中有机质: 类型、热演化与有机孔隙[J]. 地球科学, 2023, 48(12): 4641-4657.
LIU Bei.Organic matter in shales: Types, thermal evolution, and organic pores[J]. Earth Science, 2023, 48(12): 4641-4657.
[28] 柳波, 王柳, 付晓飞, 等. 页岩中固体沥青的识别、演化路径及地质意义: 以松辽盆地白垩系青山口组一段为例[J]. 石油勘探与开发, 2023, 50(6): 1173-1184.
LIU Bo, WANG Liu, FU Xiaofei, et al.Identification, evolution and geological indications of solid bitumen in shales: A case study of the first member of Cretaceous Qingshankou Formation in Songliao Basin, NE China[J]. Petroleum Exploration and Development, 2023, 50(6): 1173-1184.
[29] 付金华, 李士祥, 牛小兵, 等. 鄂尔多斯盆地三叠系长7段页岩油地质特征与勘探实践[J]. 石油勘探与开发, 2020, 47(5): 870-883.
FU Jinhua, LI Shixiang, NIU Xiaobing, et al.Geological characteristics and exploration of shale oil in Chang 7 Member of Triassic Yanchang Formation, Ordos Basin, NW China[J]. Petroleum Exploration and Development, 2020, 47(5): 870-883.
[30] 付金华, 王龙, 陈修, 等. 鄂尔多斯盆地长7页岩油勘探开发新进展及前景展望[J]. 中国石油勘探, 2023, 28(5): 1-14.
FU Jinhua, WANG Long, CHEN Xiu, et al.Progress and prospects of shale oil exploration and development in the seventh member of Yanchang Formation in Ordos Basin[J]. China Petroleum Exploration, 2023, 28(5): 1-14.
[31] 赵文智, 卞从胜, 李永新, 等. 鄂尔多斯盆地三叠系长73亚段页岩有机质转化率、排烃效率与页岩油主富集类型[J]. 石油勘探与开发, 2023, 50(1): 12-23.
ZHAO Wenzhi, BIAN Congsheng, LI Yongxin, et al.Organic matter transformation ratio, hydrocarbon expulsion efficiency and shale oil enrichment type in Chang 73 shale of Upper Triassic Yanchang Formation in Ordos Basin, NW China[J]. Petroleum Exploration and Development, 2023, 50(1): 12-23.
[32] 杨华, 席胜利, 魏新善, 等. 鄂尔多斯多旋回叠合盆地演化与天然气富集[J]. 中国石油勘探, 2006, 11(1): 17-24.
YANG Hua, XI Shengli, WEI Xinshan, et al.Evolution and natural gas enrichment of multicycle superimposed basin in Ordos[J]. China Petroleum Exploration, 2006, 11(1): 17-24.
[33] RUPPEL S C, ROWE H, MILLIKEN K, et al. Facies, rock attributes, stratigraphy,depositional environments: Yanchang Formation, Central Ordos Basin, China[J]. Interpretation, 2017, 5(2): SF15-SF29.
[34] ZHENG R H, ZENG W R, LI Z P, et al.Differential enrichment mechanisms of organic matter in the Chang 7 Member mudstone and shale in Ordos Basin, China: Constraints from organic geochemistry and element geochemistry[J]. Palaeogeography, Palaeoclimatology, Palaeoecology, 2022, 601: 111126.
[35] CHEN Z H, GUO Q L, JIANG C Q, et al.Source rock characteristics and Rock-Eval-based hydrocarbon generation kinetic models of the lacustrine Chang-7 shale of Triassic Yanchang Formation, Ordos Basin, China[J]. International Journal of Coal Geology, 2017, 182: 52-65.
[36] 程明, 罗晓容, 雷裕红, 等. 鄂尔多斯盆地张家滩页岩粉砂质夹层/纹层分布、分形特征和估算方法研究[J]. 天然气地球科学, 2015, 26(5): 845-854.
CHENG Ming, LUO Xiaorong, LEI Yuhong, et al.The distribution, fractal characteristic and thickness estimation of silty laminae and beds in the Zhangjiatan shale, Ordos Basin[J]. Natural Gas Geoscience, 2015, 26(5): 845-854.
[37] JARVIE D M.Shale resource systems for oil and gas: Part 2—shale-oil resource systems[M]//BREYER J A. Shale Reservoirs— Giant Resources for the 21st Century. Tulsa: American Association of Petroleum Geologists, 2012: 89-119.
[38] WANG Y Z, YANG J J.Quantitative classification and analysis of porosity within different lithofacies of the Upper Ordovician-Lower Silurian shales, China[J]. AAPG Bulletin, 2022, 106(8): 1653-1678.
[39] HENRY D G, JARVIS I, GILLMORE G, et al.Raman spectroscopy as a tool to determine the thermal maturity of organic matter: Application to sedimentary, metamorphic and structural geology[J]. Earth-Science Reviews, 2019, 198: 102936.
[40] ILLING C J, HALLMANN C, SCOTT A C, et al.Heterogeneity of free and occluded bitumen in a natural maturity sequence from Oligocene Lake Enspel[J]. Geochimica et Cosmochimica Acta, 2019, 245: 240-265.
[41] ESPITALIÉ J, MADEC M, TISSOT B.Role of mineral matrix in kerogen pyrolysis: Influence on petroleum generation and migration[J]. AAPG Bulletin, 1980, 64(1): 59-66.
Options
Outlines

/