The well-developed network of nano/micro-scale pores and fractures in shale formations facilitates the rapid invasion of drilling fluid into the formation under the combined effects of differential pressure and capillary force. This phenomenon significantly exacerbates wellbore instability, leading to frequent occurrences of borehole collapse. Consequently, the development of high- performance plugging materials that can effectively mitigate drilling fluid invasion and prevent pressure transmission is of paramount importance for enhancing wellbore stability in shale oil and gas formations. Currently, plugging materials for water-based drilling fluids in shale oil and gas applications primarily encompass organic, inorganic, and organic-inorganic composite nano/micro-scale materials
[11-13]. Organic nano/micro- scale plugging materials exhibit superior deformability, enabling them to undergo adaptive shape changes upon entering formation pores and microfractures. This mechanism ensures highly efficient plugging of the complex pore-fracture network in shale formations. Xie et al.
[11] synthesized a spherical nano-plugging agent via emulsion polymerization. This agent effectively packed into the nano/micro-scale pores of the filter cake, yielding a smooth and compact surface and achieving a pore-plugging efficiency of 58.33%. Lei et al.
[14] developed a self-crosslinking latex plugging agent. The agent utilizes a blend of particle sizes to physically fill the pore space in shale, while at elevated temperatures, the particles crosslink with each other, significantly reinforcing the compactness of the plugging layer. However, organic nano/micro-scale plugging agents suffer from poor thermal stability, often undergoing issues such as thermal softening, deformation, and decomposition at elevated temperatures. In contrast, inorganic plugging materials like SiO
2 and TiO
2 exhibit high rigidity and superior compressive strength, yet suffer from a strong tendency to agglomerate and poor dispersibility. Ahmed et al.
[15] developed a SiO
2/g-C
3N
4 composite inorganic nanomaterial with excellent high-temperature dispersibility and achieved a plugging efficiency of 87.2% against a ceramic sand disk. Organic-inorganic nanocomposites have become the leading research focus in plugging agent development due to their unique capability to concurrently possess both rigidity and toughness. Lei et al.
[16] designed a core-shell nano-plugging agent with a nano-SiO
2 core and a rosin-derived hydrophobic resin shell. This agent achieved a differential pressure of 24 MPa across the treated core, significantly enhancing its pressure-bearing and sealing capacity. Saleh et al.
[17] synthesized a lamellar-structured plugging agent by grafting polyacrylic acid and melamine onto graphene nanosheets. This structured material effectively plugged shale pores, thereby preventing direct contact between the shale formation and the drilling fluid. Gao
[18] developed a high-performance water-based drilling fluid system centered around a deformable micro-nano polymeric plugging agent. This system effectively mitigated the weakening of shale mechanical properties, thereby enabling the safe and efficient drilling of long horizontal sections. Researchers from Shaanxi Yanchang Petroleum (Group) Co., Ltd. developed a high-plugging- performance water-based drilling fluid system, designated HGW-1, with a density range of 1.10-1.30 g/cm³. The system was successfully deployed in a continental shale oil horizontal well in southern Yan'an, where it effectively resolved wellbore instability issues across the test section commencing at a measured depth of 1 505 m within the kick-off section corresponding to the inclination of 39.4°, to a measured total depth of 3 003 m
[19].