预出版日期: 2026-08-25
This study compares the apparent hydrogen diffusion characteristics of typical rocks, their controlling factors, and the sealing performance of different caprocks. A two-chamber gas diffusion apparatus was used to determine the apparent diffusion coefficient (Dapp) of 25 sedimentary, igneous, and metamorphic rock samples under isobaric conditions at 0.1 MPa. Representative samples were further tested for the effects of temperature, effective stress, water content, and counter-diffusing gas composition, followed by one-dimensional diffusion simulations using the measured parameters. The results show that: (1) At an effective stress of 1 MPa, Dapp ranges from 2.54×10-9 to 358.43×10-9 m2/s, with most values between 10×10-9 and 100×10-9 m2/s, and is positively correlated with porosity. Hydrogen diffusion is relatively high in sandstones, coals, and some high-porosity shales and carbonate rocks. The tested basalt, granite, and diabase samples show low to moderate diffusion, whereas the tested serpentinite and salt rock samples exhibit lower diffusion. (2) Increasing temperature from 278.15 to 318.15 K increases Dapp by 11.9%-34.4%. Increasing effective stress causes an exponential decrease in Dapp, with stress sensitivity decreasing in the order of salt rock, serpentinite, diabase, shale, sandstone, and limestone. Increasing water content markedly suppresses hydrogen diffusion. (3) Compared with N2, CH4 causes only minor changes in Dapp, whereas CO2 reduces Dapp by an average of 8.6%. (4) Increasing caprock thickness and water content reduces hydrogen diffusion and loss. Among the selected caprock samples, dry salt rock shows the strongest sealing performance, while shale performs no worse than diabase at comparable water contents. Overall, apparent hydrogen diffusion coefficient is jointly controlled by porosity, pore-throat structure, connectivity, effective stress, and water content. Caprock sealing evaluation should therefore consider lithology, thickness, effective connectivity, and in-situ water conditions.