SU Kelu, ZHONG Jiaai, WANG Wei, SHI Wenbin, CHEN Zuqing, LI Yuping, FAN Zhiwei, WANG Jianbo, LIU Yong, PAN Bei, LIU Zhicheng, JIANG Yanxia, LIANG Zirui, ZHANG Yuying, WANG Fuming
Wells CXD1 and CX2 have uncovered high-concentration potassium-and lithium-containing brines and substantial layers of halite-type polyhalite potash deposits within the 4th and 5th members of the Triassic Jialingjiang Formation and the 1st Member of Leikoupo Formation (Jia 4 Member, Jia 5 Member, and Lei 1 Member) in the Puguang area, Sichuan Basin. These discoveries mark significant breakthroughs in the exploration of deep marine potassium and lithium resources within the Sichuan Basin. Utilizing the concept of “gas-potassium-lithium integrated exploration” and incorporating drilling, logging, seismic, and geochemical data, we have investigated the geological and enrichment conditions, as well as the metallogenic model of potassium-rich and lithium-rich brines and halite-type polyhalite. First, the sedimentary systems of gypsum-dolomite flats, salt lakes and evaporated flats were developed in Jia 4 Member, Jia 5 Member, and the 1st member of Leikoupo Formation (Lei 1 Member) in northeastern Sichuan Basin, forming three large-scale salt-gathering and potassium formation centers in Puguang, Tongnanba and Yuanba, and developing reservoirs with potassium-rich and lithium-rich brines, which are favorable for the deposition of potassium and lithium resources in both solid or liquid phases. Second, the soluble halite-type polyhalite has a large thickness and wide distribution, and the reservoir brine has a high content of K+ and Li+. A solid-liquid superimposed “three-story structure” (with the lower thin-layer of brine reservoir in lower part of Jia 4 Member and Jia 5 Member, middle layer of halite-type polyhalite potash depositS, upper layer of potassium-rich and lithium-rich brine reservoir in Lei 1 Member) is formed. Third, the ternary enrichment and mineralization patterns for potassium and lithium resources were determined. Vertical superposition of polyhalite and green bean rocks is the mineral material basis of potassium-lithium resources featuring “dual-source replenishment and proximal-source release”, with primary seawater and gypsum dehydration as the main sources of deep brines, while multi-stage tectonic modification is the key to the enrichment of halite-type polyhalite and potassium-lithium brines. Fourth, the ore-forming process has gone through four stages: salt-gathering and potassium-lithium accumulation period, initial water-rock reaction period, transformation and aggregation period, and enrichment and finalization period. During this process, the halite-type polyhalite layer in Jia 4 Member and Jia 5 Member is the main target for potassium solution mining, while the brine layer in Lei 1 Member is the focus of comprehensive potassium-lithium exploration and development.